A new dibenzo[g,p]chrysene derivative, 3,6,11,14-tetramethoxyphenylamine- dibenzo[g,p]chrysene (MeOPhNDBC),.has been designed and synthesized. This material shows good hole-transport ability, high thermal stability,.and relatively high HOMO/LUMO, suitable for anode buffer in electronic devices. When 4 nm MeOPhNDBC.was inserted between the active layer and MoO3 to form double interfacial layers in the inverted polymer.solar cells based on poly (3-hexylthiophene) (P3HT) and phenyl-C61-butyric acid