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论文研究 - 瑞典西南部酸雨的健康后果
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酸雨会导致土壤和基岩中必需元素的流失,特别是在挖井水中会导致失衡,因为必需元素的浓度会降低,而有毒元素的浓度则会增加。 在这项研究中,比较了瑞典西南部72个酸性地区(pH <6> 7.0)的私人挖井。 至少喝了5年水的妇女接受了健康检查,并收集了水和头发样本。 分析了水和头发中约40种元素的浓度,主要通过ICP-MS分析。 酸中的基本元素(如钙,铬,钼,硒,钾和SO4以及人体的缓冲剂HCO3)的浓度明显低于碱性水。 与碱性水相比,酸性水以及头发中的Ca浓度中位数低6倍。 在酸性水中,HCO3的中位数低14倍。 两种人群中的镁都很相似,因为瑞典的基岩总体上镁含量低,即使碱性地区的石灰石也是如此。 特别是Ca,Cr,HCO3和SO4的浓度在pH 7.0-8.0达到峰值,这是由于碳酸盐和硫酸盐在碱性土壤中的沉淀以及从酸性土壤中的浸出所致。 在酸性井水中,Cd和Pb等有毒金属的含量明显更高。 管道中高浓度的铜特别是引起腹泻是严重的酸化问题。 这些矿泉水的每日摄入量(每天2升)对某些元素的基本成分的贡献从0%上升到30%以上,清楚地表明,通常预测,私人
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Journal of Geoscience and Environment Protection, 2018, 6, 126-142
http://www.scirp.org/journal/gep
ISSN Online: 2327-4344
ISSN Print: 2327-4336
DOI:
10.4236/gep.2018.62009 Feb. 28, 2018 126 Journal of Geoscience and Environment Protection
Health Consequences
of Acid Rain
in South West Sweden
—Influence of Acid Well Water on Health and Hair Mineral Pattern
I. Rosborg
1
, B. Nihlgård
2
1
Sustainable Development, Environmental Science and Engineering (SEED), School of Architecture and the Built Environment
(ABE), KTH Royal Institute of Technology, Stockholm, Sweden
2
Institute of Biology, Ecology Building, Lund University, Lund, Sweden
Abstract
Acid rain leads to loss of essential elements from soils and bedrock, causing an
imbalance in
especially dug well waters, as essential element concentrations
decrease and potentially toxic element concentrations increase. In this study
72 private dug wells from acid regions (pH
< 6) were compared with 68 wells
from an alkaline area on limestone bedrock (pH > 7.0) in South-western Sw
e-
den. Women, drinking the water for at least 5 years, were interviewed about
their health and water and hair samples were collected. The concentrations of
about 40 elements in water and hair were analysed, mostly by ICP-M
S. The
concentrations of essential elements such as Ca, Cr, Mo, Se, K, and SO
4
as well
as the body’s buffering agent HCO
3
were significantly lower in acid than in
alkaline water. The median Ca concentration was 6 times lower in acid waters,
and also in hair compared to alkaline. Median HCO
3
was 14 times lower in
acid waters. Mg was similar in both populations, since the Swedish bedrock in
general has low Mg content, even so limestone in the alkaline area. The co
n-
centrations of especially Ca, Cr, HCO
3
and SO
4
, peaked at pH 7.0 -
8.0, due to
precipitation of carbonates and sulphates in alkaline soils and leaching from
acid soils. The levels of toxic metals such as Cd and Pb were significantly
higher in acid well water. High Cu concentration from pipes, causing esp
e-
cially diarrhoea, is a serious acidification problem. The contribution of esse
n-
tial elements to the daily intake from these well waters, 2 Litres consumption
per day, was from 0% to above 30
% for some elements, clearly showing that
10%, which is gener
ally predicted, can be exceeded for people with private
well waters, as well as provide 0%, which is the case for many acid well waters.
How to cite this paper:
Rosborg1, I.
and
Nihlgård
, B. (2018)
Health Consequences
of Acid Rain in South West Sweden
.
Jou
r-
nal of Geoscience and Environment Pro-
tection
,
6
, 126-142.
https://doi.org/10.4236/gep.2018.62009
Received:
January 9, 2018
Accepted:
February 25, 2018
Published:
February 28, 2018
Copyright © 201
8 by authors and
Scientific
Research Publishing Inc.
This work is licensed under the Creative
Commons Attribution
International
License (CC BY
4.0).
http://creativecommons.org/licenses/by/4.0/
Open Access
I. Rosborg, B. Nihlgård
DOI:
10.4236/gep.2018.62009 127 Journal of Geoscience and Environment Protection
Water elements were mirrored in hair, e.g. Ca and Mo. The loss of essential
minerals, and increased concentration of to
xic elements in acid well water,
caused mineral imbalances in the body, as mirrored in hair. Women living
in the acid area reported more negative health changes than women in the
alkaline district, during the time they had been drinking their well water.
The number of reported heart, intestinal, muscle, and skin problems w
ere
between 2 and 9 times higher among women drinking acid than alkaline
well water.
Keywords
Acid Well Water, Hair Nutrients, Minerals, Calcium, Magnesium, Bicarbonate
,
Health
1. Introduction
Combustion of coal and oil causes emissions of SO
2
, due to the sulphur content
of coal and oil from especially proteins. Sulphur reacts with O
2
in air, forming
SO
2
gas. South-western Sweden suffered from acid rain during the 1960’-1990’s,
as the dominating south-west winds brought SO
2
in air and H
2
SO
4
in rain from
continental Europe and the British Isles. The pH of rain was generally 4 - 4.5,
and below 4 at occasions [1]. The area sometimes labelled “Acidification ba-
nana” (
Figure 1), suffered the most, since the rainfall is heaviest in this region,
and the bedrock is dominated by hard weathered primary rock bedrock,
orto-gneiss and granite, and consequently very sensitive to acidification [2].
Concentrations of mineral elements like K, Ca, Se and Cr decreased remarkably
in soil and stream water, as the nutrients were washed out of soils, and concen-
trations of toxic elements like Cd, Hg and Pb increased [3]. Fish and shellfish
died and problems with rejuvenation were frequently reported [4].
Forests were damaged due to both dry and wet deposition of acidic com-
pounds, and roots of trees were negatively influenced e.g. by aluminium com-
pound precipitates that prevented nutrients to enter roots [5].
Figure 2 is a photo from the acidified area labelled “Acidification banana”.
This area is highly sensitive to acid rain, since it is dominated by hard weathered
gneiss and granite. Spruces and pine trees are dominating species.
Contrary, the Kristianstad flatland is dominated by sandstone on primary
rock bedrock, with limestone and alkaline soils on top of the sandstone. Thus,
this area is not particularly affected by acid rain.
In a lake in a barren district between the two big lakes, Vänern and Vättern,
hundreds of crayfish were still captured in 1965, but only 12 individuals in 1970
and the shells had become soft as silk paper. Only big, old pike and perch were
captured. In 1975 blueberry jam diluted with dug well water suddenly was pur-
ple instead of dark blue, which it was only the year before, now indicating acidic
I. Rosborg, B. Nihlgård
DOI:
10.4236/gep.2018.62009 128 Journal of Geoscience and Environment Protection
Figure 1. Geological map of Sweden (SGU, Geological Survey of Sweden 2017). Studied
acid and alkaline areas.
Figure 2. A picture mirroring the specific nature in the areas of Sweden that suffered the
most from acid rain, dominated by spruce and pine trees, granite and gneiss [6].
well water. pH meter showed pH 5.8. Two years later a child got severe diar-
rhoea after drinking infant’s formula prepared on dug well water. Copper pipes
recently installed were, opposed to older pipes, bendable, as they were produced
from a soft alloy, which dissolved copper into the acid water. Water analysis
showed elevated copper concentration. Researchers had been discussing copper
from pipes due to acid well water and diarrhoea in infants for some time [7]. In-
I. Rosborg, B. Nihlgård
DOI:
10.4236/gep.2018.62009 129 Journal of Geoscience and Environment Protection
stallation of alkaline filter with dolomitic limestone reduced the acidity of water.
Thus, the water was also mineralized to some extent as the Ca concentration in-
creased from below 10 mg/L to slightly above, and the alkalinity, HCO
3
, in-
creased from about 20 mg/L to 60 mg/L. Such a filter was regenerated with
dolomitic limestone each three months. In one case, the whole family was more
alert after each re-generation of the filter, although the mineral levels were still
low. This gave an awareness of the importance of minerals from drinking water
for proper health.
In 1996 the opportunity to study Acid Rain and health effects appeared. Thus,
though long time since the negative health effects were first noticed, a scientific
study was initiated.
2. Material and Methods
2.1. Water and Hair Sampling
In the autumn 1997 47 women in an acid area and 43 in an alkaline district were
randomly selected for water and hair sampling. Since there did not exist any
public register on pH of well waters, driving around in the acid district and alka-
line area was the only way to find study subjects. Thus, during the autumn 1997
women were selected through knocking doors in the respective districts. Less
than 5% of women answering the door denied participation in the study. All
were living in private houses with private wells (dug wells, no water filter, pH < 6
(acid area) and pH > 7 (alkaline district), respectively, as tested by a field pH
meter, Knick model 912) all in the “Acidification banana”, pH < 6, dominated by
primary rock bedrock (gneiss and granite), and on the Kristianstad flatland,
pH > 7, dominated by limestone bedrock and alkaline soils [8]. Women were se-
lected if they had been drinking their specific water for at least 5 years. Three
years later another 50 women, 25 from the acid area and 25 from the alkaline,
were visited for water and hair sampling in the same regions. Hair samples were
obtained from all participants, approximately 3 cm (~0.5 g) of hair strands from
the proximal end in the occipital region. The same stainless steel scissors were
used throughout the study. Hair samples were kept in a closed envelope until the
time of analysis. A sample of 250 mL of water was collected from the kitchen tap
of the homes of all participants after half a minute of flushing to avoid corrosion
products in the samples, and filled to the top. The water samples were deep fro-
zen within 7 hours and kept in a freezer (−20˚C) until analysis at the Depart-
ment of Ecology, Lund University, Sweden. The night before the analysis, the
water samples were thawed in a refrigerator (+4˚C). No filtering of the water
took place before analysis.
2.2. Health Questionnaires
A structured health questionnaire was completed during the visit. Women were
asked about health changes related to their gastro-intestinal tract, cardiovascular
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