trans-[TcNCl2(Ph3PNH)2] - Synthesis and Structure
trans-[TcNCl2(Ph3PNH)2] � Synthesis and Structure
Ulrich Abram* and Adelheid Hagenbach
Berlin, Institut für Chemie der Freien Universität
Received April 9th, 2002
Abstract. The neutral technetium(V) phosphoraneimine complex
[TcNCl2(Ph2PNH)2] is formed when (Bu4N)[TcOCl4] reacts with
Me3SiNPPh3 in dichloromethane. Distances of 2.078(4) and
2.102(4) Å have been found between Tc and the neutral triphenyl-
phosphoraneimine ligands. The Tc-N-P
