具有T型基块的新型金属-有机配位聚合物Mn3(BTC)2(H2O)9·(H2O)的合成与结构 (2005年)

A new metal-organic polymer Mn3 (BTC)2 (H2O)9·(H2O) was synthesized by reaction of the metal ions Mn (Ⅱ) with 1,3,5-benzenetricarboxylic acid (H3BTC) in a mixed solution of DMF/C2 H5OH/H2O and crystallized. The crystal belongs to monoclinic system, space