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外文翻译-表面处理如何延长模具运行周期.doc
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How Surface Treatments Keep Molds Operating
Longer
Important tips and information about mold coatings to help you achieve the level of
production that you and your customers desire.
By Steven . Bales Mold making technology January 2006
Abstract
There’s an awful lot to know these days about molding plastic and how to get the very best performance
from the valuable tools you build or run. This guide has been written to provide important tips and
information about mold coatings. After reading this, you should have a very good idea of what
coatings—from the very traditional to the very latest—will help you to achieve the level of production you
and your customers desire. After all, these tools are an investment and they need to be protected for the life
of the products they mold.
Key Words
mold coatings preventive maintenance (PM) program benefit nickel Cobalt diamond-chrome
nickel-PTFE nickel-boron nitride electroless nickel texture
The Key Role of Coatings
Before introducing you to the wide range of coatings on the market today, it’s important to note the role
coatings can play in an effective preventive maintenance (PM) program.
PM is really the key to protecting your tooling, your investment. Why? Because it saves time and money.
Once you invest in a mold coating to improve tool performance, then a PM program is always a good idea to
ensure you get the maximum benefit. These two steps should be a given in any shop.
Remember, no coating lasts forever, and producing substandard parts from a mold with a worn coating is no
way to win customers and stay profitable. PM is probably the most cost-effective strategy you can put in
place. The key is to educate your personnel on how mold coatings wear during production. Every coating is
different, so it’s of benefit to have employees learn how to tell when the coating is showing deterioration,
especially in high-wear areas such as gates and runners.
For example, wear in and around gate areas plated with hard chrome is the first sign that your mold needs
servicing. How can you tell there is wear? The chrome coating is approximately 20 RC points harder than the
base steel, so exposed steel will wear much faster than the coated surfaces surrounding it, causing a slight
or pronounced edge or “step” on the surface.
Conversely, nickel will wear almost evenly, causing a kind of feathering effect, making it more difficult to
recognize wear. A more identifiable difference will be the color because when nickel coating wears, it
produces a shadow or halo effect on the steel. No step or edge will be evident. The steel also will have a
more silver appearance compared to the somewhat tarnished look of the nickel coating.
This knowledge makes pulling a mold for maintenance before the coating wears through an ultra important
aspect of a PM program. To miss important wear signals means more costly repairs and additional polishing
expense.
Measuring Wear
A recommended tool for measuring the wear level of any coating is an electronic thickness gauge that uses
a combination of magnetism and eddy current to accurately measure surface thickness. When the mold first
arrives in your plant, take the time to measure the surface thickness—especially in high-wear areas—using
this specialized tool. As you run production on the mold, occasionally pause to re-measure those areas.
When you have determined that the finish is wearing to a critical level, pull the mold and send it out for
maintenance.
Part Counts
Be sure to record the measurements taken with the thickness gauge and use the notes to create a history
of maintenance requirements for the tool. A cycle counter installed on the mold will allow your tooling
engineer to record wear levels as compared to piece part counts, thereby doubling the effectiveness of your
PM program. Part counts are a great way to determine maintenance needs, especially with high-volume
molding projects.
From the very first time you run the mold, keep an accurate piece count until it is ready for its first
maintenance work. Use that count as a gauge for when the next maintenance is due. Because you know
approximately when the mold will be ready to be refurbished, you can arrange the service in advance with
your coating vendor. This not only gives him ample time to schedule your mold maintenance, but it also
allows you to optimize the use of the mold and the machine that’s running it.
Coating Challenges
Even today, there are those who question the benefits of using fancy—sometimes more
expensive—coatings to prolong tooling life or enhance performance. To some, the tried and true hard
chrome or electroless nickel are all they’ll ever need to accomplish those goals. But we all know that today’s
engineered plastic materials can be pretty rough on injection molds.
Challenges to mold maintenance extend beyond glass- and mineral-fillers to include rice hulls, wood fibers,
metal powders, flame retardants and other additives—not to mention the resins themselves. In addition,
outgassing and moisture acidity often accompany abrasive wear, taking an even bigger toll on expensive
tooling.
In addition, growing complexity in mold design involves tinier, more intricate flow passages and more
frequent use of moving cores and slides. All of these circumstances have prompted the development of a
wider variety of mold coatings that can keep molds operating longer between repairs.
New Coating Science
If you are molding highly intricate parts using glass-filled materials, you might think using hard chrome will
be sufficient because it is a classic, reliable way to protect your mold from both corrosion and abrasion.
However, hard chrome, for all its benefits, does not tend to plate uniformly in detailed areas like ribs and
bosses. There is a newer solution—a nickel-cobalt alloy coating that can overcome that limitation.
Nickel Cobalt
Nickel-cobalt can be an economical alternative to hard chrome. Hard chrome requires construction of a
conforming anode to coat the mold. The more detail in the mold, the more time it takes to build the anode
and the more expensive the process becomes. This nickel-cobalt alloy coating requires no anode, and
because of its electroless properties, it plates much more uniformly.
The cobalt gives it good abrasion resistance, but its hardness is 62 RC, 10 points lower than hard chrome.
Is it worth paying extra for hard chrome’s superior wear protection? You have to consider the material being
run in the mold. What’s the percentage of glass? Is corrosion a greater concern than abrasion?
Diamond Chrome
Hard chrome and a nickel-cobalt alloy coating offer two very good solutions for abrasion resistance, but for
very high-wear conditions, an even newer product called diamond-chrome offers exceptional protection.
It has an RC rating greater than 85 and is a chromium-matrix composite coating with a dispersion of
nanometer-size, spherical diamond particles. Since diamonds are unmatched for hardness, this coating
offers protection beyond the norm. Though their Rockwell ratings are comparable, diamond-chrome
outperforms titanium nitride (TiN) coating because it won’t compromise the dimensional integrity of the
plated tool. The difference is that it is applied at only about 130oF while TiN requires application
temperatures of 800oF or higher.
Diamond-chrome can plate prehardened, heat-treated or nitrided steel and other base materials such as
aluminum, beryllium-copper, brass and stainless steel. Recommended uses include cores, cavities, slides,
ejector sleeves, and rotating and unscrewing cores. Its anti-galling properties are advantageous on moving
cores and slides.
Diamond-chrome also is very strippable and has no adverse effect on the base material, saving time and
money when maintenance is needed. TiN is strippable as well, but it can take up to several days to remove
with a peroxide-based solution. Diamond-chrome can be stripped in minutes using reverse electrolysis in a
caustic solution.
In addition, diamond-chrome can be deposited at any controlled thickness from 20 millionths of an inch to
0.001 in. TiN is generally only applied in thin deposits of a few millionths of an inch. Diamond-chrome can
coat complex details, while TiN has very limited coverage of complex details. While TiN is very lubricious,
with a coefficient of friction (COF) of 0.4 (against steel), diamond-chrome has a COF of 0.15—nearly three
times more lubricious.
Nickel-Boron Nitride
When it comes to molders’ needs for a specialty coating that offers excellent release properties and high
resistance to wear, heat, and corrosion, an electroless nickel-phosphorus matrix containing boron nitride
particles should be considered.
It has a very low COF (0.05 against steel) and an RC hardness of 54, which can be increased to 67 RC after
heat treating—a unique characteristic. Nickel-boron nitride can be applied to any substrate at only 185oF
and can be easily stripped without compromising the base material. Though it is approximately 20 percent
more expensive than nickel-PTFE, this coating will outperform nickel-PTFE at up to 1250oF, which far
surpasses the 500oF maximum limit for all PTFE-based coatings.
Because applying nickel-boron nitride is an autocatalytic process, it requires no anode, therefore saving
time and money. In addition, it will not compromise thermal conductivity of the mold. Applications include
unscrewing cores for closures, where reduced cycle times are essential.
Where lubricity is needed for better release from deep ribs, zero-draft cores, textured surfaces and “sticky”
polymers, a nickel-PTFE composite will greatly improve part release and enhance resin flow by as much as
4 to 8 percent for shorter cycle times. COF is 0.10 against steel.
It should be noted that applying pure PTFE to the mold adds high lubricity, but only a very short-term
benefit. PTFE by itself has no hardness, so it won’t last. But a dispersion of 25 percent PTFE by volume in a
co-deposit with nickel results in 45 RC hardness for added wear and corrosion protection.
Tried and True
Despite the new coating science, we cannot throw out the old, reliable coatings such as like hard chrome or
electroless nickel just yet. There’s no question that they still have their uses.
Hard Chrome
For example, hard chrome’s top advantage is that it has a hardness of 72 Rockwell C (RC) and is applied at
the low temperature of 130oF. When applied in its purest form, it allows you to achieve any SPI finish on
your tooling.
Hard chrome is often a good choice for electrical circuit-breaker molds since they use materials containing
as much as 40 percent glass. To help combat erosion and prevent severely damaging gates and surrounding
mold areas, it is usually recommend to use a high-diamond polish, followed by a hard-chrome coating of
0.0003 to 0.0005 inches for added protection.
The downside can be cost, since chrome plating is limited to areas accessible by an anode. If your mold has
complex details, it could require extra conforming anode construction and that adds time and expense to the
project. Another possible drawback is chrome’s environmental impact—chromium is a carcinogen. Some
companies are attempting to develop better, cleaner alternatives, but so far nothing matches hard chrome’s
benefits from a tooling perspective.
Electroless Nickel
Like hard chrome, electroless nickel has been used successfully for years, particularly to protect molds
where corrosive off-gassing is created by materials such as PVC or halogenated fire retardants. It is not
uncommon to see such resins produce an orange rust, corroding the unprotected mold almost right before
your eyes. Products molded of such materials for the electronic or medical industry often cannot tolerate the
presence of any oxidation byproducts.
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