Multiple magnification effects of Ce
3+
ions on
near-infrared persistent luminescence of Cr-
doped LaAlO
3
Yi Zhang,
1
Rui Huang,
2,3,
* Zhenxu Lin,
1
Jie Song,
2
Xiang Wang,
2
Yanqing Guo,
2
Chao
Song,
2
Ying Yu,
1
and John Robertson
3
1
Institute of Nanoscience and Nanotechnology, Central China Normal University, Wuhan 430079, China
2
Department of Physics and Electronic Engineering, Hanshan Normal University, Chaozhou, Guangdong 521041,
China
3
Department of Engineering, University of Cambridge, Cambridge, UK
*
rhuang@hstc.edu.cn
Abstract: Ce
3+
/Cr
3+
co-doped LaAlO
3
for near-infrared (NIR) long lasting
phosphors were synthesized through solid-state reaction. Incorporation of
Ce
3+
ions into Cr
3+
-doped LaAlO
3
significantly enhanced the NIR persistent
luminescence by more than one order of magnitude compared with LaAlO
3
doped with Cr
3+
. Detailed analysis of the photoluminescence,
photoluminescence excitation, and Thermo-luminescence spectra, as well as
the persistent decay behavior of Ce
3+
/Cr
3+
co-doped LaAlO
3
, indicated that
the improvement of NIR persistent luminescence at around 735 nm (Cr
3+
:
2
E→
4
A
2
transition) is not only originated from a persistent energy transfer
process from Ce
3+
ions to Cr
3+
ions, but also attributed to the extra efficient
traps created by incorporation of Ce
3+
ions. The current work develops an
alternative approach toward the efficient NIR Cr
3+
-doped non-gallate long-
persistence phosphors.
©2016 Optical Society of America
OCIS codes: (160.2540) Fluorescent and luminescent materials; (160.2900) Optical storage
materials; (160.4670) Optical materials; (160.4760) Optical properties.
References and links
1. D. Jia, R. S. Meltzer, W. M. Yen, W. Jia, and X. Wang, “Green phosphorescence of CaAl
2
O
4
: Tb
3+
, Ce
3+
through
persistence energy transfer,” Appl. Phys. Lett. 80(9), 1535–1537 (2002).
2. J. S. Kim, P. E. Jeon, J. C. Choi, H. L. Park, S. I. Mho, and G. C. Kim, “Warm-white-light emitting diode
utilizing a single-phase full-color Ba
3
MgSi
2
O
8
:Eu
2+
, Mn
2+
phosphor,” Appl. Phys. Lett. 84(15), 2931–2933
(2004).
3. B. Liu, C. Shi, and Z. Qi, “Potential white-light long-lasting phosphor: Dy
3+
-doped aluminate,” Appl. Phys. Lett.
86(19), 191111 (2005).
4. C.-H. Huang, T.-W. Kuo, and T.-M. Chen, “Novel red-emitting phosphor Ca
9
Y(PO
4
)
7
:Ce
3
+,Mn
2+
with energy
transfer for fluorescent lamp application,” ACS Appl. Mater. Interfaces 2(5), 1395–1399 (2010).
5. H. Lin, J. Xu, Q. Huang, B. Wang, H. Chen, Z. Lin, and Y. Wang, “Bandgap tailoring via Si doping in inverse-
garnet Mg
3
Y
2
Ge
3
O
12
:Ce
3+
persistent phosphor potentially applicable in AC-LED,” ACS Appl. Mater. Interfaces
7(39), 21835–21843 (2015).
6. R. Zhong, J. Zhang, X. Zhang, and S. Lu, “Red phosphorescence in Sr
4
Al
14
O
25
: Cr
3+
,Eu
2+
,Dy
3+
through persistent
energy transfer,” Appl. Phys. Lett. 88, 201916 (2006).
7. T. Maldiney, A. Lecointre, B. Viana, A. Bessière, M. Bessodes, D. Gourier, C. Richard, and D. Scherman,
“Controlling electron trap depth to enhance optical properties of persistent luminescence nanoparticles for in
vivo imaging,” J. Am. Chem. Soc. 133(30), 11810–11815 (2011).
8. V. Caratto, F. Locardi, G. A. Costa, R. Masini, M. Fasoli, L. Panzeri, M. Martini, E. Bottinelli, E. Gianotti, and
I. Miletto, “NIR persistent luminescence of lanthanide ion-doped rare-earth oxycarbonates: the effect of
dopants,” ACS Appl. Mater. Interfaces 6(20), 17346–17351 (2014).
9. Z. Li, J. Shi, H. Zhang, and M. Sun, “Highly controllable synthesis of near-infrared persistent luminescence
SiO
2
/CaMgSi
2
O
6
composite nanospheres for imaging in vivo,” Opt. Express 22(9), 10509–10518 (2014).
10. R. Pang, Y. Jia, R. Zhao, H. Li, J. Fu, W. Sun, L. Jiang, S. Zhang, C. Li, and Q. Su, “Tunable long lasting
phosphorescence due to the selective energy transfer from defects to luminescent centres via tunnelling in Mn
2+
and Tm
3+
co-doped zinc pyrophosphate,” Dalton Trans. 43(25), 9661–9668 (2014).
#257457
Received 15 Jan 2016; revised 8 Feb 2016; accepted 8 Feb 2016; published 25 Feb 2016
© 2016 OSA
1 Mar 2016 | Vol. 6, No. 3 | DOI:10.1364/OME.6.000922 | OPTICAL MATERIALS EXPRESS 922
剩余6页未读，继续阅读
资源评论
weixin_38646659
- 粉丝: 6
- 资源: 922
最新资源
- 基于Spring boot 的Starter机制提供一个开箱即用的多数据源抽取工具包，计划对RDMS(关系型
- 水泵系统水力计算公式-标准版
- Wesley是一套为经销商量身定制的全业务流程渠道 分销管理系统（手机APP称为经销商管家）
- Adaptive Autosar EM 标准规范
- 鼓谱图片转MuseScore超文本文档实验程序
- 自动驾驶感知动态障碍物算法上车效果 （Xavier jetson&autoware）
- 【实验指导书-2024版】实验一：查验身份证.doc
- 如何批量多级文件夹图片合并PDF,怎么批量多级文件夹图片转换PDF,快速将大量多个文件夹的图片转PDF，多张图片转换成PDF
- SpringBoot3.3 实现停止/重启定时任务的代码
- Adaptive Autosar 规范
资源上传下载、课程学习等过程中有任何疑问或建议，欢迎提出宝贵意见哦~我们会及时处理！
点击此处反馈
