一种2，2’-联咪唑化合物的水热合成和晶体结构(2013年)资源-CSDN文库

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第

34

卷第

5

期

2013

年

9

月

ζJ

03

Nm

q

,,"

A

丛丁

3

叩

uws

井冈山大学学报(自然科学版)

Journal

of

Jinggangshan

University

(N

atural

Science)

19

文章编号

1674-8085(2013)05-0019-04

SOLVOTHER

岛

IAL

PREPARATION AND CRYSTAL

STRUCTURE

OF

A

2

，

2'-BII

1\但

DAZOLE

COMPOUND

*CHEN

Wen-tong1

气

KUANG

Han-mao

1

,2,

CHEN

Hua-Iong

1

,2

(1.

In

stitute

of

Ap

pliedαemis

町;

Jinggangshan

U:回

versity

，

Ji'an,

Jiangxi

343009

,

China;

2.

SchoolofChemis

往

y

and

Chemical

Engineering

,

Jinggangshan

University

,

Ji'

血，

Jiangxi

343009

,

China)

Abstract:

A biimidazole-containing compound,

(H

30)(2,2'-biimidazole)Cl (1), has been obtained through solvothennal

reactions and

struc

阳

rally

characterized

by

single-crystal X-ray

di

岱

action.

Compound 1 crystallizes in the space group

C2/m

of

the monoclinic system with

four

岛

rmula

units in a cell: a =

16

.5

760

份，

b = 1

1.

5546(4), c = 4.6180(1) A, ß =

96.382(2

沪，

V = 879.00(4) A

3

, C

Jf

9C1N40

, M

r

= 188.62,

Dc

=

1.

425 glcm

3

, S =

1.

022

，

μ(MoKα)

= 0

.3

93

mm-

1

,

F(OOO)

=

392

, R = 0.0454 and

wR

= 0.1298. Compound 1 is characteristic

of

a 2-D supramolecular layer moti

f.

Compound 1

displays an emission

in

也

e

blue region.

Key

words:

biimidazole;

crystal;

如

orescence;

solvothermal; supramolecular

CLC

number:0641

Document

code:A

DOI:

1O.3

969/j.issn.1674-8085.2013.05.005

一种

2

，

2'-

联咪瞠化合物的水热合成和晶体结构

*陈文通

12

，匡汉茂

1

气陈华龙

1

，

2

(l.井冈山大学应用化学研究所，江西，吉安

343009;

2.

井冈山大学化学化工学院，江西，吉安.

343009)

摘

要:通过溶剂热反应法合成了一种

22·

联咪唾化合物(H

30

)(2

,

2'

-biimi

也

zole)CI

(1)

，并对该化合物进行

了

x-

射线单晶结构分析。标题化合物属于单斜晶系的

C2/m

空间群，晶胞参数如下

a

=

16.5760(4)

, b =

1

1.

5546(4)

, c =

4.6180

(1)

A

，

β=

96

.3

82(2)0

,

V=

879.00(4)

A

3

,

CJI9CIN40

, M; =

188.62

, Dc =

1.

425

g/

cm

3

, S =

1.

022

，以

Mo

Ki

α)

=

0.393

mm-

1

,

F(OOO)

=

392

, R

=.0.0454

和

wR

=

0

.1

298

。该化合物具有二维超分子结构。该

化合物能够发出蓝色荧光。

关键词

z

联咪略:晶体:荧光;溶剂热;超分子

中图分类号

0641

文献标识码

A

DOI: 10

.3

969/J.issn.

1674-8085

却

13.05.006

INTRODUCTION

use

of

selιassemblyωyield

novel

compounds

by

virtue

of

different.

kinds

of

weak

intermolecular

cooperative

interactions

,

such

as

aromatic

π-

1[

stacking

interactions

,

hydrogen

bonding

interactions

,

ion-ion

interactions

,

ion-dipole

interactions

and

dipole-dipole

interactions

,

to

interlink

building

subunits

together

Supramolecular

chemistry

has

recently

obtained

more

and

more

interest

to

prepare

novel

solid

state

compounds

because

supramolecular

chemis

位

y

makes

R

臼

eived

date:

2013

-0

5-06

Mωified

date:

2013

-0

7

-0

7

Foundation

item:

Th

e

science

and

t

，创

mology

proj

臼

t

of

Jiangxi

Pr

ovincial

Departm

ent

of

Ed

u

倡.ti

on

(GJ

Jl

I535).

Biogr

叩

hi

臼:

.CHEN

悦

n-tong

(1973

寸"

male

,

bom

in

Guti

an,

Fujian

province

,

P

hD.，翻侃

iate

Pr

o

f.,

major

in

structure

chemistry(E-mail:

毗

chen_2(

削@y

ah

∞

.cn);

KUANG

Han-mao

(1963

寸，

male

,

bom

in

Ji'an

,

Jiangxi

provin

饵，

bachelor

，臼

Sωiate

Pr

o

f.,

major

in

physi

臼

I

chemistry

(E-mail:

kl

h2m3

@126.com);

CHEN

Hua-Iong

(1976

寸，

male

,

bom

in

Ji'

姐，

Jiangxi

province

,

m

臼

ter

，

associate

Prof.,

major

in

physical

chemistry

(E-

mail:

chenhI88@163.ωm).

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