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Modern Electric, Hybrid Electric, and Fuel Cell Vehicles Fundame...
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1
Environmental Impact and History of
Modern Transportation
CONTENTS
1.1 Air Pollution ..................................................................................................2
1.1.1 Nitrogen Oxides................................................................................2
1.1.2 Carbon Monoxide ............................................................................3
1.1.3 Unburned Hydrocarbons ................................................................3
1.1.4 Other Pollutants ................................................................................3
1.2 Global Warming ............................................................................................4
1.3 Petroleum Resources ....................................................................................5
1.4 Induced Costs ................................................................................................7
1.5 Importance of Different Transportation Development Strategies
to Future Oil Supply......................................................................................9
1.6 History of Electric Vehicles ........................................................................13
1.7 History of Hybrid Electric Vehicles ..........................................................15
1.8 History of Fuel Cell Vehicles......................................................................17
References ..............................................................................................................18
The development of internal combustion engine vehicles, especially auto-
mobiles, is one of the greatest achievements of modern technology.
Automobiles have made great contributions to the growth of modern soci-
ety by satisfying many of its needs for mobility in everyday life. The rapid
development of the automotive industry, unlike that of any other industry,
has prompted the progress of human society from a primitive one to a highly
developed industrial society. The automotive industry and the other indus-
tries that serve it constitute the backbone of the word’s economy and
employ the greatest share of the working population.
However, the large number of automobiles in use around the world has
caused and continues to cause serious problems for the environment and
human life. Air pollution, global warming, and the rapid depletion of the
Earth’s petroleum resources are now problems of paramount concern.
In recent decades, the research and development activities related to trans-
portation have emphasized the development of high efficiency, clean, and
1
© 2005 by CRC Press LLC
safe transportation. Electric vehicles, hybrid electric vehicles, and fuel cell
vehicles have been typically proposed to replace conventional vehicles in the
near future.
This chapter reviews the problems of air pollution, gas emissions causing
global warming, and petroleum resource depletion. It also gives a brief
review of the development of electric vehicles, hybrid electric vehicles, and
fuel cell technology.
1.1 Air Pollution
At present, all vehicles rely on the combustion of hydrocarbon fuels to
derive the energy necessary for their propulsion. Combustion is a reaction
between the fuel and the air that releases heat and combustion products. The
heat is converted to mechanical power by an engine and the combustion
products are released into the atmosphere. A hydrocarbon is a chemical
compound with molecules made up of carbon and hydrogen atoms. Ideally,
the combustion of a hydrocarbon yields only carbon dioxide and water,
which do not harm the environment. Indeed, green plants “digest” carbon
dioxide by photosynthesis. Carbon dioxide is a necessary ingredient in veg-
etal life. Animals do not suffer from breathing carbon dioxide unless its con-
centration in air is such that oxygen is almost absent.
Actually, the combustion of hydrocarbon fuel in combustion engines is
never ideal. Besides carbon dioxide and water, the combustion products con-
tain a certain amount of nitrogen oxides (NO
x
), carbon monoxides (CO), and
unburned hydrocarbons (HC), all of which are toxic to human health.
1.1.1 Nitrogen Oxides
Nitrogen oxides (NO
x
) result from the reaction between nitrogen in the air
and oxygen. Theoretically, nitrogen is an inert gas. However, the high tem-
peratures and pressures in engines create favorable conditions for the for-
mation of nitrogen oxides. Temperature is by far the most important
parameter in nitrogen oxide formation. The most commonly found nitrogen
oxide is nitric oxide (NO), although small amounts of nitrogen dioxide
(NO
2
) and traces of nitrous oxide (N
2
O) are also present. Once released into
the atmosphere, NO reacts with oxygen to form NO
2
. This is later decom-
posed by the Sun’s ultraviolet radiation back to NO and highly reactive oxy-
gen atoms that attack the membranes of living cells. Nitrogen dioxide is
partly responsible for smog; its brownish color makes smog visible. It also
reacts with atmospheric water to form nitric acid (HNO
3
), which dilutes in
rain. This phenomenon is referred to as “acid rain” and is responsible for the
destruction of forests in industrialized countries.
1
Acid rain also contributes
to the degradation of historical monuments made of marble.
1
2 Modern Electric, Hybrid Electric, and Fuel Cell Vehicles
© 2005 by CRC Press LLC
1.1.2 Carbon Monoxide
Carbon monoxide results from the incomplete combustion of hydrocarbons
due to a lack of oxygen.
1
It is a poison to human and animal beings that
breathe it. Once carbon monoxide reaches the blood cells, it fixes to the
hemoglobin in place of oxygen, thus diminishing the quantity of oxygen that
reaches the organs and reducing
2
the physical and mental abilities of affected
living beings. Dizziness is the first symptom of carbon monoxide poisoning,
which can rapidly lead to death. Carbon monoxide binds more strongly to
hemoglobin than oxygen. The bonds are so strong that normal body func-
tions cannot break them. Persons intoxicated by carbon monoxide must be
treated in pressurized chambers, where the pressure makes the carbon
monoxide–hemoglobin bonds easier to break.
1.1.3 Unburned Hydrocarbons
Unburned hydrocarbons are a result of the incomplete combustion of hydro-
carbons.
1, 2
Depending on their nature, unburned hydrocarbons may be
harmful to living beings.
2
Some of these unburned hydrocarbons may be
direct poisons or carcinogenic chemicals such as particulates, benzene, or
others. Unburned hydrocarbons are also responsible for smog: the Sun’s
ultraviolet radiations interact with unburned hydrocarbons and NO in the
atmosphere to form ozone and other products. Ozone is a molecule formed
of three oxygen atoms. It is colorless but very dangerous, and poisons as it
attacks the membranes of living cells, thus causing them to age prematurely
or to die. Toddlers, older people, and asthmatic humans suffer greatly from
exposure to high ozone concentrations. Annually, deaths from high ozone
peaks in polluted cities are reported.
3
1.1.4 Other Pollutants
Impurities in fuels result in the emission of pollutants. The major impurity is
sulfur, which is mostly found in diesel and jet fuel and also in gasoline and
natural gas.
1
The combustion of sulfur (or sulfur compounds such as hydro-
gen sulfide) with oxygen releases sulfur oxides (SO
x
). Sulfur dioxide (SO
2
) is
the major product of this combustion. Upon contact with air, it forms sulfur
trioxide, which later reacts with water to form sulfuric acid, a major compo-
nent of acid rain. It should be noted that sulfur oxide emissions originate
from transportation sources, but also largely from the combustion of coal in
power plants and steel factories. In addition, there is debate over the exact
contribution of natural sources such as volcanoes.
Petroleum companies add chemical compounds to their fuels in order to
improve the performance or lifetime of engines.
1
Tetraethyl lead, often
referred to simply as “lead,” was used to improve the knock resistance of
gasoline and therefore allow for better engine performance. However, the
Environmental Impact and History of Modern Transportation 3
© 2005 by CRC Press LLC
combustion of this chemical releases lead metal, which is responsible for a
neurological disease called “saturnism.” Its use is now forbidden in most
developed countries and it has been replaced by other chemicals.
1
1.2 Global Warming
Global warming is a result of the “greenhouse effect” induced by the pres-
ence of carbon dioxide and other gases, such as methane, in the atmosphere.
These gases trap the Sun’s infrared radiation reflected by the ground, thus
retaining the energy in the atmosphere and increasing the temperature. An
increased Earth temperature results in major ecological damages to its
ecosystems and in many natural disasters that affect human populations.
2
Among the ecological damages induced by global warming, the disap-
pearance of some endangered species is a concern because it destabilizes the
natural resources that feed some populations. There are also concerns about
the migration of some species from warm seas to previously colder northern
seas, where they can potentially destroy indigenous species and the
economies that live off those species. This may be happening in the
Mediterranean Sea, where barracudas from the Red Sea have been observed.
Natural disasters command our attention more than ecological disasters
because of the amplitude of the damage they cause. Global warming is
believed to have induced meteorological phenomena such as “El Niño,”
which disturbs the South-Pacific region and regularly causes tornadoes,
inundations, and dryness. The melting of the polar icecaps, another major
result of global warming, raises the sea level and can cause the permanent
inundation of coastal regions, and sometimes of entire countries.
Carbon dioxide is the result of the combustion of hydrocarbons and coal.
Transportation accounts for a large share (32% from 1980 to 1999) of carbon
dioxide emissions. The distribution of carbon dioxide emissions is shown in
4
tion sector is clearly now the major contributor of carbon dioxide emissions.
It should be noted that developing countries are rapidly increasing their
world’s population. Further discussion is provided in the next subsection.
The large amounts of carbon dioxide released in the atmosphere by
human activities are believed to be largely responsible for the increase in
important to note that carbon dioxide is indeed digested by plants and
sequestrated by the oceans in the form of carbonates. However, these natu-
ral assimilation processes are limited and cannot assimilate all of the emitted
carbon dioxide, resulting in an accumulation of carbon dioxide in the atmos-
phere.
4 Modern Electric, Hybrid Electric, and Fuel Cell Vehicles
© 2005 by CRC Press LLC
Figure 1.1.
transportation sector, and these countries represent a very large share of the
Figure 1.2 shows the trend in carbon dioxide emissions. The transporta-
global Earth temperature observed during recent decades (Figure 1.3). It is
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